Hexamethylditin 六甲基二錫

規格: 98%
CAS: 661-69-8
產品編號: H66089
MDL: MFCD00008277
品牌: INFI
Chemical Name六甲基二錫
Synonym 六甲基乙基烯 TD-5032 六甲基二錫烷 HEXAMETHYLDITIN Tin, hexamethyldi- Trimethyltin dimer hexamethyldi-stannan Stannane, hexamethyldi- Distannane, hexamethyl- HEXAMETHYLDITIN(IV) 六甲基二錫 TD 5032 HEXAMETHYLDISTANNANE Hexamethylditin,95%
CAS Number661-69-8
PubChem Substance ID6327618
EC Number211-549-2
Beilstein Registry Number4(4)4346
MDL NumberMFCD00008277
Reaxys-RN3600327
Chemical Name Translation六甲基二錫
Wiswesser Line Notation1-SN-1&1&-SN-1&1&1
InChIKeyCCRMAATUKBYMPA-UHFFFAOYSA-N
LabNetwork Molecule IDLN00001309
InChIInChI=1S/6CH3.2Sn/h6*1H3;;
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7690 ug/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - excitement
   Behavioral - ataxia
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555199

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 53800 ug/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555183

WGK Germany2
Hazard statements
  • H300+H310+H330
  • H330 Fatal if inhaled 吸入致命
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 對水生生物毒性非常大并具有長期影響。
  • H310 Fatal in contact with skin 皮膚接觸致命
  • H300 Fatal if swallowed 吞食致命
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Hazard Codes T+,N
    RTECSWH8280000
    Precautionary statements
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
    • P305+P351+P338
    • P304+P340+P310
    • P501 Dispose of contents/container to..… 處理內容物/容器.....
    • P302+P350
    • P403+P233
    • P302+P352+P310+P361+P364
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通風良好的地方使用。
    • P284 Wear respiratory protection.? 佩戴呼吸保護裝置。
    • P270 Do not eat, drink or smoke when using this product. 使用本產品時不要吃東西,喝水或吸煙。
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或醫生/醫師。
      Signal word Danger
      UN Number 3146
      Risk Statements
      • R24 Toxic in contact with skin 與皮膚接觸有毒
      • R28 Very toxic if swallowed 吞咽極毒
      • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮膚接觸及吞食都有劇毒
      • R50/53
        Safety Statements
        • S60 This material and its container must be disposed of as hazardous waste 該物質及其容器必須作為危險廢物處置;
        • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴適當的防護服、手套和眼睛/面保護;
        • S20 When using do not eat or drink 使用時,不得進食,飲水;
        • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 發生事故時或感覺不適時,立即求醫(可能時出示標簽);
        • S27/28
        • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸后,立即用大量水沖洗并征求醫生意見;
        • S27 Take off immediately all contaminated clothing 立即脫掉全部污染的衣服;
        • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮膚接觸后,立即用大量…(由生產廠家指定)沖洗;
        • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免釋放到環境中,參考特別指示/安全收據說明書;
          Storage condition Air Sensitive
          Packing GroupII
          Hazard Class6.1
        • {SA}
        • 1. Tetrahedron Lett. 47 , 8973, (2006)
        • {SA}
        • 2. Tetrahedron Lett. 47 , 8607, (2006)
        • {SA}
        • Beil. 4 ,IV,4346
        • {SA}
        • Fieser 6 ,273 / Fieser 13 ,142 / Fieser 17 ,143
        • {SA}
        • Corp MSDS 1 (1), 1851:C / FT-IR 2 (3), 4477:C / FT-NMR 1 (3), 737:B / RegBook 1 (2), 3043:C / Sax 6 , 1521 / Structure Index 1 , 481:B:6 / Vapor Phase 3 , 1682:A
        • {uni_hamburg} Short: II/25D
        • Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms
        • Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
        • Editor: Kuchitsu, K.
        • Source: Landolt-B?rnstein, New Series
        • Volume: II/25D
        • Year: 2003
        • Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules
        • ISBN: 3-540-42860-7
        • ISBN: 978-3-540-42860-2
        • Internet Resource: DOI:10.1007/b75952
        • RefComment: VIII, 569 pages. Hardcover
        • RefComment: Written for scientists and researchers in the fields of chemistry and physics
        • Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
        • {uni_hamburg} Short: III/35C4
        • Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and
        • 661-69-8 H66089 Hexamethylditin
六甲基二錫

          化學屬性

          Mol. Formula(CH3)3SnSn(CH3)3
          Mol. Weight328
          Boiling Point182°C(lit.)
          Density1.58 g/mL at 20 °C(lit.)
          Melting Point23-24 °C(lit.)
          Refractive index1.5410
          Flash Point61°C(lit.)
          TSCANo
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